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41.
Anastasia O. Kolesnikova Dmitry A. Kornilov Aidar T. Gubaidullin Vladimir D. Kiselev 《国际化学动力学杂志》2020,52(5):301-309
The kinetic parameters and enthalpies of the Diels–Alder reactions between cyclopentadiene and 2,3-dicyano-1,4-benzoquinone leading to the formation of two different monoadducts and bisadduct were determined. The stability of adducts is compared. Monoadduct appears to be thermodynamically more stable than the bisadduct. Comparison with the other Diels–Alder reactions studied previously allows us to conclude that the heat effects upon formation of the considered Diels–Alder adducts are the lowest in comparison with all the studied dienophiles. 相似文献
42.
Leiqing Hu Sankhajit Pal Hien Nguyen Vinh Bui Haiqing Lin 《Journal of polymer science. Part A, Polymer chemistry》2020,58(18):2467-2481
Over the last two decades, polymers with superior H2/CO2 separation properties at 100–300 °C have gathered significant interest for H2 purification and CO2 capture. This timely review presents various strategies adopted to molecularly engineer polymers for this application. We first elucidate the Robeson's upper bound at elevated temperatures for H2/CO2 separation and the advantages of high-temperature operation (such as improved solubility selectivity and absence of CO2 plasticization), compared with conventional membrane gas separations at ~35 °C. Second, we describe commercially relevant membranes for the separation and highlight materials with free volumes tuned to discriminate H2 and CO2, including functional polymers (such as polybenzimidazole) and engineered polymers by cross-linking, blending, thermal treatment, thermal rearrangement, and carbonization. Third, we succinctly discuss mixed matrix materials containing size-sieving or H2-sorptive nanofillers with attractive H2/CO2 separation properties. 相似文献
43.
Guiqiang Cao Zhikang Wang Da Bi Prof. Jing Zheng Prof. Qingxue Lai Prof. Yanyu Liang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(45):10314-10320
Lithium-sulfur batteries have been considered as potential electrochemical energy-storage devices owing to their satisfactory theoretical energy density. Nonetheless, the inferior conversion efficiency of polysulfides in essence leads to fast capacity decay during the discharge/charge cycle. In this work, it is successfully demonstrated that the conversion efficiency of lithium polysulfides is remarkably enhanced by employing a well-distributed atomic-scale Fe-based catalyst immobilized on nitrogen-doped graphene (Fe@NG) as a coating of separator in lithium-sulfur batteries. The quantitative electrocatalytic efficiency of the conversion of lithium polysulfides is determined through cyclic voltammetry. It is also proven that the Fe-NX configuration with highly catalytic activity is quite beneficial for the conversion of lithium polysulfides. In addition, the adsorption and permeation experiments distinctly indicate that the strong anchoring effect, originated from the charge redistribution of N doping into the graphene matrix, inhibits the movement of lithium polysulfides. Thanks to these advantages, if the as-prepared Fe@NG catalyst is combined with polypropylene and applied as a separator (Fe@NG/PP) in Li-S batteries, a high initial capacity (1616 mA h g−1 at 0.1 C), excellent capacity retention (93 % at 0.2 C, 70 % at 2 C), and superb rate performance (820 mA h g−1 at 2 C) are achieved. 相似文献
44.
Matthew L. Gettings Michael T. Thoenen Dr. Edward F. C. Byrd Dr. Jesse J. Sabatini Dr. Matthias Zeller Prof. Dr. Davin G. Piercey 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(64):14530-14535
This work reports the first compound containing both a tetrazole and an azasydnone ring, a unique energetic material. Several energetic salts of the tetrazole azasydnone were synthesized and characterized, leading to the creation of new secondary and primary explosives. Molecular structures are confirmed by 1H and 13C NMR, IR spectroscopy, and X-ray crystallographic analysis. The high heats of formation, fast detonation velocities, and straight-forward synthesis of energetic azasydnones should capture the attention of future energetics research. 相似文献
45.
Dr. Tao Yang Prof. Yan Song Dr. Xiaodong Tian Prof. Huaihe Song Prof. Zhanjun Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16514-16520
Pitch has been used to prepare electrodes by high-temperature heat treatments for supercapacitors, lithium-ion batteries, on account of its rich aromatic ring structure. Here, the toluene-soluble component of pitch is used to prepare a kind of laminated carbon. This was realized by a template-free synthesis at low temperature with the addition of pressure. The toluene-soluble component has a small molecular weight, which makes the thermal deformation ability stronger and then enhances the orientation of the carbon layer with the help of pressure. The prepared anode exhibits a splendid electrochemical performance compared with the traditional graphite anode. A high stable capacity of approximately 550 mAh g−1 at 50 mA g−1, which is much higher than graphite (372 mAh g−1), is obtained. Also, when the current density is up to 2 A g−1, the capacity is about 150 mAh g−1. Surprisingly, it also delivers a superior cycling performance. And when used as the anode/cathode electrode for lithium-ion capacitors, a high energy density can be obtained. The present work offers an opportunity to utilize the pitch source in lithium energy storage with promising cycle life, high energy/power density, and low cost. 相似文献
46.
We fabricate F-doped and F-S-codoped diamond-like carbon (DLC) films using plasma-enhanced chemical vapor deposition system. The hardness, Raman spectra, and high-vacuum tribological behaviors indicate that the films are DLC films. The hardness is close related to the tribological properties of DLC films under high vacuum. The high hardness of DLC films would be helpful for obtaining the long lifetime under high vacuum. The lifetimes of F-S-codoped DLC films are about 120 and 140 seconds, which is attributed to the fast graphitization under high vacuum. The lifetime of F-doped DLC films is prolonged to the value of around 300 and 440 seconds, X-ray photoelectron spectroscopy analysis exhibits the existence of the “adsorption” F, and transmission electron microscopy analysis shows that the “adsorption” F could react with Fe to form layered FeF2 nanocrystal at the initial sliding, which could be helpful for prolonging the lifetime of F-doped DLC films under high vacuum. This investigation opens a new window to overcome the disadvantage of F, S-doped DLC films under high vacuum. 相似文献
47.
Yu Liu Xian-Hua Li Qiu-Li Li Guo-Qiang Tang 《Surface and interface analysis : SIA》2020,52(5):214-223
A zircon U–Pb dating method with a high spatial resolution of 2- to 3-μm was successfully implemented by using Cameca IMS-1280HR SIMS in this study. Homemade cathode and modified intermediate pole were used to improve the intrinsic performance of duoplasmatron ion source. An O− primary beam with intensity of approximately 3 μA and stability of 0.68% over 40 minutes was achieved and could be used continuously for more than 240 hours under high current conditions. Under Gaussian illumination mode, a 2- to 3-μm O− primary beam was obtained with an intensity of approximately 200 pA. Four standard zircons, namely, 91500, Temora, Plešovice, and Qinghu, were dated using the 2- to 3-μm high spatial resolution U–Pb isotopic analysis, yielding U–Pb ages consistent with their recommended values, within errors. Our work shows that zircon U–Pb dating with high accuracy and spatial resolution can be achieved, on the basis of a series of duoplasmatron modification and instrumental optimization. 相似文献
48.
All-organic composites are widely used in energy storage application due to the high breakdown strength performance, but the improvement of energy storage was limited by the relatively low dielectric constant. Therefore, to satisfy the high demands of dielectric materials, energy storage properties of polymer composites should be further enhanced. In this article, poly(vinylidene fluoride-co-chlorotrifluoroethylene) (P(VDF-CTFE)) and polyurea (PUA), which are known as high dielectric ferroelectric material and linearly high energy storage efficiency material respectively, are composited through double layer (DL) casting method for the first time. The properties of DL structured composite film is contrasted with solution blending structure especially in energy storage efficiency, and the results demonstrate that DL structure design can make great use of advantages of two materials and also can avoid the influence of phase separation between P(VDF-CTFE) and PUA efficiently. Moreover, high breakdown strength (6180 kV/cm) and high energy storage efficiency (77%) of DL composites can be realized simultaneously by incorporating PUA as an insulating layer, and the mechanism is discussed in detail. This work provides an effective route to improve the energy storage properties of polymer dielectric materials and shows great application potential. 相似文献
49.
ABSTRACTNano-polycrystalline diamonds (NPDs) have become fundamental tools for cutting-edge X-ray absorption spectroscopy (XAS) studies at high P/T conditions that opened up new research directions by overcoming previous limitations. Indeed, NPDs yield a continuous and weak X-ray background signal which enables the collection of high-quality XAS data of materials compressed in diamond anvil cells. This is a critical advantage over the classically used single-crystal diamonds that generate strong parasitic signals (glitches) which render the analysis of XAS data in many cases impossible. In this contribution we give an overview of the impact and the scientific opportunities that NPDs opened up for extreme condition XAS spectroscopy at the European Synchrotron Radiation Facility and discuss future needs. 相似文献
50.
为了提高三阶WENO-Z格式在极值点处的计算精度,通过理论推导给出三阶WENO格式满足收敛精度的充分条件。采用泰勒级数展开的方式,推导给出所构造格式非线性权重的计算公式,并综合权衡计算精度和计算稳定性确定所构造格式的参数。通过两个典型的精度测试,验证了改进格式在光滑流场极值点区域逼近三阶精度。进一步选用激波与熵波相互作用和Richtmyer-Meshkov不稳定性等经典算例,证实了本文提出的改进格式WENO-PZ3相较其他格式(WENO-JS3和WENO-Z3)不仅具有较高的精度,而且降低了格式的耗散,提高了对流场结构的分辨率。 相似文献